Time Domain Zero Field NMR and NQR*
نویسندگان
چکیده
für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namensnennung 4.0 Lizenz. Time Domain Zero Field NMR and NQR*
منابع مشابه
Zero field NMR and NQR with selective pulses and indirect detection
Zero field NMR and NQR spectra are obtained by the application of dc magnetic field pulses to a demagnetized sample. Pulsed dc fields allow for selective excitation of isotopic species and provide a means for coherent manipulation of the spin system in zero field. Using these selective pulses and level crossing techniques, indirect detection of a quadrupolar nucleus may be accomplished via prot...
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Time-domain zero-field NQR methods are used to determine quadrupole coupling constants and asymmetry parameters for a variety of polycrystalhne solids. Results for aliphatic and aromatic groups are reported. Several cases are presented in which sites with small differences in quadrupole coupling constants are resolved, and very smah (CO. 1) asymmetry parameters are measured. Structure in the ze...
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In zero-field NMR [ 1.21, a sample is subjected to a time-dependent magnetic field which cycles between a high value, Bo, and zero field. The B. field is useful for preparation and high-sensitivity detection of the spins. Evolution occurs for a variable time tl in zero field. This yields sharp crystal-like NMR spectra from polycrystalline samples, where ordinarily only powder patterns are obser...
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Methods are described and demonstrated for detecting the coherent evolution of nuclear spin observables in zero magnetic field with the full sensitivity of high field NMR. The principle motivation is to provide a means of obtaining solid state spectra of the magnetic dipole and electric quadrupole interactions of disordered systems without the line broadening associated with random orientation ...
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We report the results of 27Aland 93Nbnuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) measurements in PrNb2Al20 single crystals. The field angle dependence of the observed 93Nb-NMR lines for the single crystal at around 5 T and at 50K is reproduced by a simulation using previously reported NQR parameters νQ,Nb ≈ 1.82MHz and ηNb ≈ 0, while 27Al-NMR lines were not reproduce...
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